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Traditional Water Purification Methods: Limitations and the Need for Advanced Solutions
- Chemical Contaminants: Industrial pollutants, agricultural chemicals, and other dissolved impurities remain in the water.
- Toxic Elements: Dangerous substances such as Arsenic, Fluoride, Nitrates, and Pesticide residues are not removed through boiling, copper vessels, or sand
- Microbial Contaminants: Complex microbes are resistant to heat or physical filtration.
(I) Chlorine in Water Treatment
An Overview of Chlorine
Chlorine has been a cornerstone of municipal water treatment for over a century, playing a pivotal role in combating waterborne diseases. As a potent disinfectant, chlorine neutralises a wide array of pathogens, viruses and protozoa. Its main advantage is its ability to maintain a residual presence in water, thereby ensuring ongoing protection as the water travels through various flows (eg; pipes to homes, schools, and businesses). This property alone makes chlorine indispensable in large-scale water distribution systems.
Mechanism of Action
The Advantages of Chlorine
- Cost-Effectiveness and Accessibility: Chlorine is relatively inexpensive and widely available, making it the go-to solution for municipalities, especially in developing
- Broad-Spectrum Efficacy: Chlorine demonstrates broad-spectrum efficacy, successfully targeting and eliminating various pathogens, including bacteria, viruses, and protozoa.
- Residual Disinfection: Chlorine’s residual action protects water from recontamination during distribution, ensuring safety up to the point of use.
However, the use of Chlorine also bears a few challenges –
Challenges Associated with Chlorine
- Formation of Harmful By-Products: Chlorine reacts with organic matter to form disinfection by-products (DBPs) such as trihalomethanes (THMs) and haloacetic acids (HAAs), which are linked to health risks like cancer.
- Taste and Odour Challenges: Chlorinated water often has an unpleasant taste and
- Corrosive Effects: Chlorine’s corrosive nature can damage pipes and infrastructure, leading to higher maintenance costs and potential damage.
While chlorine remains the predominant choice for municipal water treatment, these challenges have led researchers and engineers to explore alternative solutions.
Among these, silver has emerged as a promising option, particularly for specialized applications where chlorine’s limitations are most problematic.
(II) Silver as an Agent in Water Treatment
Overview of Silver
Silver’s use in water purification dates back centuries. Today, silver is emerging as a modern alternative for water disinfection due to its ability to eliminate microorganisms effectively without forming harmful by-products. Silver is extremely adaptable, especially in niche applications like hospitals and spacecraft, where ultra-pure water is critical.
Mechanism of Action
Silver ions (Ag⁺) exert their antimicrobial effect through several mechanisms. They bind to microbial proteins and nucleic acids, disrupting essential cellular functions like respiration and DNA replication. This interference ultimately kills the microorganisms.
Silver ions maintain their antimicrobial activity even after binding with bacterial proteins, making them highly efficient. Moreover, the unique properties of silver ions enable them to regenerate. Silver ions are effective even at low concentrations, such as 60 parts per billion (ppb). Silver can eliminate 99.99% of bacteria like Pseudomonas aeruginosa upon contact, demonstrating its potency and reliability
The Advantages of Silver
- Zero Toxic Residue: Unlike chlorine, silver does not react with organic matter to produce toxic by-products, ensuring a safer and more environmentally friendly disinfection process.
- Efficacy: Silver ions achieve potent antibacterial results at remarkably low concentrations, as low as 60 ppb.
- Long-Lasting Antimicrobial Activity: Silver’s ability to regenerate and remain effective over time reduces the need for frequent application.
Some Challenges Associated with Silver
- Higher Cost: Silver is significantly more expensive than chlorine, limiting its use in large-scale municipal systems.
- Environmental Impact: High concentrations of silver can be toxic to aquatic life if
- Aquatic Toxicity: Silver contamination in water bodies may pose a risk to
Conclusion
Chlorination continues to dominate municipal water treatment due to its affordability and broad-spectrum efficacy. However, its limitations, such as DBP formation and taste issues, highlight the need for safer alternatives, like silver.
It offers a promising option for niche applications, particularly where environmental sustainability and taste are priorities.
The choice between chlorine and silver hinges on factors like cost, scale, and public health priorities, ensuring consistent and large-scale disinfection. NICHEM has been working in the drinking water purification segment for more than 10 years to develop niche products.
About NICHEM
Long-standing Specialty Chemicals player with ISO 9001:2015 certification and a history of providing specialty solutions for over 25 years. The company is headed by senior chemical industry specialists with the combined expertise of more than 100 years. With an emphasis on eco-friendly, non-toxic products, the company’s primary strength is research, development, and customization. More information on NICHEM can be found at https://nichem.solutions.
References:
- National Water Development Agency. (n.d.). Status of trace and toxic metals in Indian rivers.
https://www.nwda.gov.in/upload/uploadfiles/e-book/S-4/Status-of-Trace-and- Toxic-Metals-in-Indian-Rivers.pdf - Safe Drinking Water (2017, January 23). What is chlorination?
https://www.safewater.org/fact-sheets-1/2017/1/23/what-is-chlorination - World Health (2017). Chlorine in drinking water: Background document for development of WHO guidelines for drinking water quality. Guidelines for drinking-water quality (4th ed.). National Center for Biotechnology Information (NCBI).
https://www.ncbi.nlm.nih.gov/books/NBK506911/ - The Silver (n.d.). Silver in water purification.
https://silverinstitute.org/silver-water-purification/